Research Article Details
| Article ID: | A38004 |
| PMID: | 12530899 |
| Source: | J Org Chem |
| Title: | Electrochemical synthesis of alkyl nitroaromatic compounds. |
| Abstract: | Alkyl nitroaromatic compounds were readily prepared via nucleophilic aromatic substitution for hydrogen or a heteroatom by electrochemical oxidation of the sigma-complex. Butyllithium and butylmagnesium chloride were used as nucleophiles, and several nitrocompounds were tested to explore the possibilities of the NASH and NASX reactions promoted electrochemically. |
| DOI: | 10.1021/jo025898k |
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